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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%

CAS: 56602-33-6 | C12H22F6N6OP2 | 442.287 g/mol

256.00 DKK - 2415.00 DKK

Chemical Identifiers

CAS 56602-33-6
Molecular Formula C12H22F6N6OP2
Molecular Weight (g/mol) 442.287
MDL Number MFCD00011948
InChI Key MGEVGECQZUIPSV-UHFFFAOYSA-N
Synonym bop reagent, 1h-benzo d 1,2,3 triazol-1-yl oxy tris dimethylamino phosphonium hexafluorophosphate v, castro's reagent, bop-reagent, benzotriazol-1-yloxytris dimethylamino-phosphonium hexafluorophosphate, ccris 2602, castros reagent, tri dimethylamino benzotriazol-1-yloxyphosphonium hexafluorophosphate, benzotriazol-1-yloxy tris dimethylamino phosphonium hexafluorophosphate, 1h-benzotriazol-1-yloxytris dimethylamino phosphonium hexafluorophosphate
PubChem CID 151348
IUPAC Name benzotriazol-1-yloxy-tris(dimethylamino)phosphanium;hexafluorophosphate
SMILES CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F
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11443187
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Thermo Scientific Alfa Aesar
A16140.03
1 g
256.00 DKK
1g
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11453187
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Thermo Scientific Alfa Aesar
A16140.06
5 g
609.00 DKK
5g
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11463187
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Thermo Scientific Alfa Aesar
A16140.14
25 g
2415.00 DKK
25g
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Description

Description

1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

Solubility
Soluble in methanol, acetone and dichloromethane. Insoluble in water.

Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.
Specifications
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Seguridad y manipulación

Seguridad y manipulación

GHS H Statement
H228-H315-H319-H335
Flammable solid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P210-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

missing translation for 'dotInformation' : Transport Hazard Class: 4.1; Packing Group: II; Proper Shipping Name: FLAMMABLE SOLIDS, ORGANIC, N.O.S.

Recommended Storage : 2° to 8°C

SDS
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Certificados

RUO – Research Use Only

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1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate, 98%

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