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3-Bromopyridine, 98+%, Thermo Scientific Chemicals

Product Code. 11495333
25 g
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25 g
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3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

Solubility
Soluble in water (31 g/L at 20°C).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong acids.

Chemical Identifiers

CAS 626-55-1
Molecular Formula C5H4BrN
Molecular Weight (g/mol) 158.00
MDL Number MFCD00006373
InChI Key NYPYPOZNGOXYSU-UHFFFAOYSA-N
Synonym 3-pyridyl bromide, pyridine, 3-bromo, 3-bromo pyridine, 3-bromo-pyridine, 5-bromopyridine, unii-xmn8h2xe9h, 5-bromo pyridine, xmn8h2xe9h, 3-pyridylbromide, 3-bromopryidineShow MoreShow Less
PubChem CID 12286
ChEBI CHEBI:51575
IUPAC Name 3-bromopyridine
SMILES BrC1=CC=CN=C1

Specifications

Melting Point -27°C
Density 1.617
Boiling Point 172°C to 174°C
Flash Point 72°C (181°F)
Odor Characteristic
Refractive Index 1.57
Quantity 25 g
UN Number UN2810
Beilstein 105880
Solubility Information Soluble in water (31g/L at 20°C).
Formula Weight 158
Percent Purity ≥98%
Chemical Name or Material 3-Bromopyridine
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Certificates

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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number2666554A Certificate TypeCertificate of Analysis Date21/02/2025 Catalog NumberA12894.22,A12894.36,A12894.14
Lot Number10252258 Certificate TypeCertificate of Analysis Date02/09/2024 Catalog NumberA12894.22,A12894.14,A12894.36
Lot Number10243044 Certificate TypeCertificate of Analysis Date23/08/2022 Catalog NumberA12894.22,A12894.14,A12894.36
Lot Number5001P24S Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA12894.22,A12894.14,A12894.36
Lot NumberD9221C Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA12894.22,A12894.14,A12894.36

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