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3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals

Product Code. 15475305
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Quantity:
50 mL
This item is not returnable. View return policy
This item is not returnable. View return policy

Description

 

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Palladium-catalyzed coupling with [4-(methoxycarbonyl)benzyllzinc bromide then selective hydrolysis of the tert-butyl ester trifluoroacetic acid, in design and synthesis of pyridone-containing inhibitors.

Solubility
TRUSTED_SUSTAINABILITY

Specifications

CAS 131379-39-0
Density 0.976
Molecular Formula C6H11BrO2Zn
Linear Formula CH3CH2O2C(CH2)3ZnBr
MDL Number MFCD00671977
Quantity 50 mL
UN Number UN3399
Sensitivity Air sensitive
Synonym zinc 2+ ion 4-ethoxy-4-oxobutan-1-ide bromide
Solubility Information Reacts with water.
InChI Key XPARCVGSTPKNNR-UHFFFAOYSA-M
SMILES CCOC(=O)CC[CH2-].[Zn+]Br
IUPAC Name bromozinc(1+);ethyl butanoate
Molecular Weight (g/mol) 260.436
PubChem CID 4390801
Formula Weight 260.44
Chemical Name or Material 3-(Ethoxycarbonyl)propylzinc bromide, Packaged under Argon in resealable ChemSeal™ bottles
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Safety and Handling

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Product Identifier
  • 3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 4
  • Carcinogenicity Category 2
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity Category 3
  • Substance which\, in contact with water\, emits flammable gases Category 1
 Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H260-In contact with water releases flammable gases which may ignite spontaneously.
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H335-May cause respiratory irritation.
  • H336-May cause drowsiness or dizziness.
  • H351-Suspected of causing cancer.
  • EUH019-May form explosive peroxides.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P231+P232-Handle under inert gas. Protect from moisture.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
  • P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.
 Supplemental information
  • MIXTURE LIST-Contains : Tetrahydrofuran, 3-(Ethoxycarbonyl)propylzinc bromide

RUO – Research Use Only

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