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Borane-2-methylpyridine complex, 95%, Thermo Scientific Chemicals
707.83 DKK - 3239.25 DKK
Chemical Identifiers
CAS | 3999-38-0 |
---|---|
Molecular Formula | C6H10BN |
Molecular Weight (g/mol) | 106.96 |
MDL Number | MFCD07784361 |
InChI Key | ZMASBEFBIXMNCP-UHFFFAOYSA-N |
Synonym | 2-Picoline borane complex |
IUPAC Name | 2-methylpyridine borane |
SMILES | B.CC1=CC=CC=N1 |
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
---|---|---|---|---|---|---|---|---|---|
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
15442799
|
Thermo Scientific Alfa Aesar
H66642.06 |
5 g |
707.83 DKK
5g |
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15452799
|
Thermo Scientific Alfa Aesar
H66642.14 |
25 g |
3239.25 DKK
25g |
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Description
Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsUsed as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.
Solubility
Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
Notes
Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
Chemical Identifiers
3999-38-0 | |
106.96 | |
ZMASBEFBIXMNCP-UHFFFAOYSA-N | |
2-methylpyridine borane |
C6H10BN | |
MFCD07784361 | |
2-Picoline borane complex | |
B.CC1=CC=CC=N1 |
Specifications
3999-38-0 | |
White | |
C6H10BN | |
UN2813 | |
2-Picoline borane complex | |
ZMASBEFBIXMNCP-UHFFFAOYSA-N | |
2-methylpyridine borane | |
106.96 | |
Solid |
44°C to 50°C | |
100°C (212°F) | |
MFCD07784361 | |
Moisture sensitive | |
Slightly sol; in water,cyclohexane,very sol; in methanol,THF,diglyme,and benzene | |
B.CC1=CC=CC=N1 | |
106.96 | |
95% | |
Borane-2-methylpyridine complex |
Safety and Handling
GHS H Statement
H261-H315-H319-H335
In contact with water releases flammable gas.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P223-P231+P232-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P335+P334-P362-P370+P378q-P501c
H261-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: WATER-REACTIVE SOLID, N.O.S.
missing translation for 'tsca' : No
missing translation for 'storageNote' : 2° to 8°C
Recommended Storage : Keep cold; Store under Argon
- Borane-2-methylpyridine complex
Signal Word
- Danger
Hazard Category
- Serious eye damage/eye irritation Category 2
- Skin corrosion/irritation Category 2
- Specific target organ toxicity Category 3
- Substance which\, in contact with water\, emits flammable gases Category 2
Hazard Statement
- H261-In contact with water releases flammable gases.
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
- H335-May cause respiratory irritation.
- EUH014-Reacts violently with water.
Precautionary Statement
- P231+P232-Handle under inert gas. Protect from moisture.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P302+P352-IF ON SKIN: Wash with plenty of water/soap.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P312-Call a POISON CENTER/doctor/if you feel unwell.
- P332+P313-If skin irritation occurs: Get medical advice/attention.
- P337+P313-If eye irritation persists: Get medical advice/attention.
Supplemental information
- MIXTURE LIST-Contains : Borane-2-methylpyridine
RUO – Research Use Only