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Borane-2-methylpyridine complex, 95%, Thermo Scientific Chemicals

707.83 DKK - 3239.25 DKK

Chemical Identifiers

CAS 3999-38-0
Molecular Formula C6H10BN
Molecular Weight (g/mol) 106.96
MDL Number MFCD07784361
InChI Key ZMASBEFBIXMNCP-UHFFFAOYSA-N
Synonym 2-Picoline borane complex
IUPAC Name 2-methylpyridine borane
SMILES B.CC1=CC=CC=N1
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15442799
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Thermo Scientific Alfa Aesar
H66642.06
5 g
707.83 DKK
5g
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15452799
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Thermo Scientific Alfa Aesar
H66642.14
25 g
3239.25 DKK
25g
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Description

Description

Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

Solubility
Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene

Notes
Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
Specifications

Chemical Identifiers

3999-38-0
106.96
ZMASBEFBIXMNCP-UHFFFAOYSA-N
2-methylpyridine borane
C6H10BN
MFCD07784361
2-Picoline borane complex
B.CC1=CC=CC=N1

Specifications

3999-38-0
White
C6H10BN
UN2813
2-Picoline borane complex
ZMASBEFBIXMNCP-UHFFFAOYSA-N
2-methylpyridine borane
106.96
Solid
44°C to 50°C
100°C (212°F)
MFCD07784361
Moisture sensitive
Slightly sol; in water,cyclohexane,very sol; in methanol,THF,diglyme,and benzene
B.CC1=CC=CC=N1
106.96
95%
Borane-2-methylpyridine complex
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Safety and Handling

Safety and Handling

GHS H Statement
H261-H315-H319-H335
In contact with water releases flammable gas.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P223-P231+P232-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P335+P334-P362-P370+P378q-P501c

H261-H315-H319-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: WATER-REACTIVE SOLID, N.O.S.

missing translation for 'tsca' : No

missing translation for 'storageNote' : 2° to 8°C

Recommended Storage : Keep cold; Store under Argon

Product Identifier
  • Borane-2-methylpyridine complex

Signal Word
  • Danger

Hazard Category
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
  • Substance which\, in contact with water\, emits flammable gases Category 2

Hazard Statement
  • H261-In contact with water releases flammable gases.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
  • EUH014-Reacts violently with water.

Precautionary Statement
  • P231+P232-Handle under inert gas. Protect from moisture.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
  • P332+P313-If skin irritation occurs: Get medical advice/attention.
  • P337+P313-If eye irritation persists: Get medical advice/attention.

Supplemental information
  • MIXTURE LIST-Contains : Borane-2-methylpyridine

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only