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Propargyl bromide, 80% in toluene, stab. with MgO, Thermo Scientific Chemicals

Product Code. 11477907
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Description

Propargyl bromide, 80% in toluene is used to prepare betulonic acid-peptide conjugates with anti-inflammatory activity and propargylic amines employed in enyne metathesis. It finds application in the propargylation of spiro ketones, allylic alcohols and enone complexes. In Barbier-type reaction, it reacts with aldehydes to give alkyne alcohols. It is actively involved in the synthesis of polyethylene glycol (PEG) and peptide-grafted polyesters.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Propargyl bromide, 80% in toluene is used to prepare betulonic acid-peptide conjugates with anti-inflammatory activity and propargylic amines employed in enyne metathesis. It finds application in the propargylation of spiro ketones, allylic alcohols and enone complexes. In Barbier-type reaction, it reacts with aldehydes to give alkyne alcohols. It is actively involved in the synthesis of polyethylene glycol (PEG) and peptide-grafted polyesters.

Solubility
Miscible with ethanol, ether, benzene, carbon tetrachloride and chloroform. Immiscible with water.

Notes
Light sensitive. Store in a cool place. Incompatible withbases, strong oxidizing agents, copper, peroxides, silver, silver oxides, mercury and mercury oxides.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 106-96-7
Molecular Formula C3H3Br
Molecular Weight (g/mol) 118.961
MDL Number MFCD00000241
InChI Key YORCIIVHUBAYBQ-UHFFFAOYSA-N
Synonym propargyl bromide, 3-bromopropyne, 3-bromo-1-propyne, 1-propyne, 3-bromo, 2-propynyl bromide, propynyl bromide, 1-bromo-2-propyne, propyne, 3-bromo, gamma-bromoallylene, 1-brom-2-propin
PubChem CID 7842
IUPAC Name 3-bromoprop-1-yne
SMILES C#CCBr

Specifications

Melting Point -61°C
Density 1.335
Boiling Point 88°C to 90°C
Flash Point 3°C (37°F)
Refractive Index 1.494
Quantity 50 mL
UN Number UN2924
Beilstein 605309
Sensitivity Light sensitive
Solubility Information Miscible with ethanol,ether,benzene,carbon tetrachloride and chloroform. Immiscible with water.
Formula Weight 118.97
Concentration or Composition (by Analyte or Components) 80% in toluene
Chemical Name or Material Propargyl bromide, stabilized with MgO
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